51 research outputs found
Generating functionals, consistency, and uniqueness in the integral equation theory of liquids
We discuss and illustrate through numerical examples the relations between
generating functionals, thermodynamic consistency (in particular the
virial-free energy one), and uniqueness of the solution, in the integral
equation theory of liquids. We propose a new approach for deriving closures
automatically satisfying such characteristics. Results from a first exploration
of this program are presented and discussed.Comment: 27 pages, 5 figure
Phase behavior of a fluid with competing attractive and repulsive interactions
Fluids in which the interparticle potential has a hard core, is attractive at
moderate separations, and repulsive at greater separations are known to exhibit
novel phase behavior, including stable inhomogeneous phases. Here we report a
joint simulation and theoretical study of such a fluid, focusing on the
relationship between the liquid-vapor transition line and any new phases. The
phase diagram is studied as a function of the amplitude of the attraction for a
certain fixed amplitude of the long ranged repulsion. We find that the effect
of the repulsion is to substitute the liquid-vapor critical point and a portion
of the associated liquid-vapor transition line, by two first order transitions.
One of these transitions separates the vapor from a fluid of spherical
liquidlike clusters; the other separates the liquid from a fluid of spherical
voids. At low temperature, the two transition lines intersect one another and a
vapor-liquid transition line at a triple point. While most integral equation
theories are unable to describe the new phase transitions, the Percus Yevick
approximation does succeed in capturing the vapor-cluster transition, as well
as aspects of the structure of the cluster fluid, in reasonable agreement with
the simulation results.Comment: 15 pages, 20 figure
Mean Field Renormalization Group for the Boundary Magnetization of Strip Clusters
We analyze in some detail a recently proposed transfer matrix mean field
approximation which yields the exact critical point for several two dimensional
nearest neighbor Ising models. For the square lattice model we show explicitly
that this approximation yields not only the exact critical point, but also the
exact boundary magnetization of a semi--infinite Ising model, independent of
the size of the strips used. Then we develop a new mean field renormalization
group strategy based on this approximation and make connections with finite
size scaling. Applying our strategy to the quadratic Ising and three--state
Potts models we obtain results for the critical exponents which are in
excellent agreement with the exact ones. In this way we also clarify some
advantages and limitations of the mean field renormalization group approach.Comment: 16 pages (plain TeX) + 8 figures (PostScript, appended),
POLFIS-TH.XX/9
Cluster variation method and disorder varieties of two-dimensional Ising-like models
I show that the cluster variation method, long used as a powerful hierarchy
of approximations for discrete (Ising-like) two-dimensional lattice models,
yields exact results on the disorder varieties which appear when competitive
interactions are put into these models. I consider, as an example, the
plaquette approximation of the cluster variation method for the square lattice
Ising model with nearest-neighbor, next-nearest-neighbor and plaquette
interactions, and, after rederiving known results, report simple closed-form
expressions for the pair and plaquette correlation functions.Comment: 10 revtex pages, 1 postscript figur
Direct entropy determination and application to artificial spin ice
From thermodynamic origins, the concept of entropy has expanded to a range of
statistical measures of uncertainty, which may still be thermodynamically
significant. However, laboratory measurements of entropy continue to rely on
direct measurements of heat. New technologies that can map out myriads of
microscopic degrees of freedom suggest direct determination of configurational
entropy by counting in systems where it is thermodynamically inaccessible, such
as granular and colloidal materials, proteins and lithographically fabricated
nanometre-scale arrays. Here, we demonstrate a conditional-probability
technique to calculate entropy densities of translation-invariant states on
lattices using limited configuration data on small clusters, and apply it to
arrays of interacting nanometre-scale magnetic islands (artificial spin ice).
Models for statistically disordered systems can be assessed by applying the
method to relative entropy densities. For artificial spin ice, this analysis
shows that nearest-neighbour correlations drive longer-range ones.Comment: 10 page
Cluster variation - Pade` approximants method for the simple cubic Ising model
The cluster variation - Pade` approximant method is a recently proposed tool,
based on the extrapolation of low/high temperature results obtained with the
cluster variation method, for the determination of critical parameters in
Ising-like models. Here the method is applied to the three-dimensional simple
cubic Ising model, and new results, obtained with an 18-site basic cluster, are
reported. Other techniques for extracting non-classical critical exponents are
also applied and their results compared with those by the cluster variation -
Pade` approximant method.Comment: 8 RevTeX pages, 3 PostScript figure
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